DSM : Thesis SL-DSM-14-0060

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Research field

Chemistry / Solid state physics, chemistry and nanosciences
Solid state physics, surfaces and interfaces / Solid state physics, chemistry and nanosciences

Title

Molecular synthesis for tunable magnetic supramolecular self-assembly

Abstract

In this projet, we will synthesis non-magnetic and magnetic molecules to form two-dimensional magnetic nanoarchitectures. The non magnetic molecules will be used to form a host network and the magnetic molecules will be the guest. The magnetic molecules will be derivative of phtalocyanine et porphyrine molecule. These molecules can accept a magnetic atom in their squeleton center. The non-magnetic molecules will be prepared from perylene and melamine derivatives. O, H, N, Cl substituant will be added to the molecules in order they self-assemble into open-networks through hydrogen bonds. Molecular self-assembly and stability (with molecular ratio and temperature) will be investigated using scanning tunneling microscopy.

This molecular system is a model system for organic spintronics.

Location

Institut rayonnement et matière de Saclay
Service de Physique de l'Etat Condensé
Laboratoire d'Electronique et nanoPhotonique Organique
Centre : Saclay
Starting date : 01/10/2014

Contact person

Bruno Jousselme
CEA / DSM/IRAMIS/NIMBE/LICSEN
Bât. 466, p. 14.

91191 Gif sur Yvette




Phone : 01 69 08 91 91

University / Graduate School

Ecole Polytechnique
Ecole Doctorale de l'Ecole Polytechnique - Ecole Polytechnique -

Thesis supervisor

Fabien SILLY
CEA / DSM/IRAMIS/SPEC/LEPO
Dr Fabien Silly

CEA Saclay

DSM-IRAMIS-SPCSI

Bâtiment 462

F-91191 Gif-Sur-Yvette Cedex

France


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